Salta al contenuto principale
Home

Dedicated to discovery

  • A proposito di ELGA
    • A proposito di ELGA
    • Carriere
    • Eventi
  • Supporto
    • Laboratory Planning
  • Contatti
  • EN
  • DE
  • ES
  • FR
  • PT
  • EN-US
Home
  • Prodotti
    • PURELAB
      • PURELAB® Dispenser
      • PURELAB® Flex
      • PURELAB® Quest
      • PURELAB® Pharma Compliance
      • PURELAB® Chorus 1 Complete
      • PURELAB® Chorus 1
      • PURELAB® Chorus 2
      • PURELAB® Chorus 3
      • PURELAB® Chorus 2 +
    • CENTRA
      • CENTRA® R60/120
      • CENTRA® R200
      • CENTRA® RDS
    • MEDICA
      • MEDICA® 150
      • MEDICA® 7/15
      • MEDICA® BIOX 2024
      • MEDICA® Pro-R & Pro-RE
      • MEDICA® R200
      • MEDICA® EDI 15/30
      • MEDICA® Pro-LPS
      • MEDICA® Pro EDI 60/120
      • MEDICA® BIOX
      • Hubgrade
    • BIOPURE
      • BIOPURE® 300/600
    • PURENERGY® 30
    • ELGA Gamma Completa di Prodotti
  • Applicazioni
    • Analisi microbiologica
    • Biochimica clinica
    • Colture cellulari
    • Cromatografia liquida
      • High Performance Liquid Chromatography
    • Elettrochimica
    • Gascromatografia
    • Genetica
    • High Performance Liquid Chromatography (HPLC)
    • Immunochimica
    • Requisiti dell'acqua per laboratori generici
    • Spettrofotometria
    • Spettrometria di massa
    • Spettroscopia atomica
  • Tecnologie
    • Activated Carbon
    • Electrodeionization (EDI)
    • Filtration
    • Ion Exchange
    • PureSure
    • Reverse Osmosis
    • Ultraviolet
  • Impurità nell'acqua
    • Dissolved Gases
    • Inorganic Compounds
    • Microorganisms & Bacteria
    • Organic Compounds
    • Particulates
  • Conoscenza
    • BROSCHÜREN
    • Blog
    • Casi di studio
    • Acqua ultrapura
    • Guide e libri bianchi
  • Where to buy
  • Contattaci
Home
  • Contattaci
  • Prodotti
    • PURELAB
      • PURELAB® Dispenser
      • PURELAB® Flex
      • PURELAB® Quest
      • PURELAB® Pharma Compliance
      • PURELAB® Chorus 1 Complete
      • PURELAB® Chorus 1
      • PURELAB® Chorus 2
      • PURELAB® Chorus 3
      • PURELAB® Chorus 2 +
    • CENTRA
      • CENTRA® R60/120
      • CENTRA® R200
      • CENTRA® RDS
    • MEDICA
      • MEDICA® 150
      • MEDICA® 7/15
      • MEDICA® BIOX 2024
      • MEDICA® Pro-R & Pro-RE
      • MEDICA® R200
      • MEDICA® EDI 15/30
      • MEDICA® Pro-LPS
      • MEDICA® Pro EDI 60/120
      • MEDICA® BIOX
      • Hubgrade
    • BIOPURE
      • BIOPURE® 300/600
    • PURENERGY® 30
    • ELGA Gamma Completa di Prodotti
  • Applicazioni
    • Analisi microbiologica
    • Biochimica clinica
    • Colture cellulari
    • Cromatografia liquida
      • High Performance Liquid Chromatography
    • Elettrochimica
    • Gascromatografia
    • Genetica
    • High Performance Liquid Chromatography (HPLC)
    • Immunochimica
    • Requisiti dell'acqua per laboratori generici
    • Spettrofotometria
    • Spettrometria di massa
    • Spettroscopia atomica
  • Tecnologie
    • Activated Carbon
    • Electrodeionization (EDI)
    • Filtration
    • Ion Exchange
    • PureSure
    • Reverse Osmosis
    • Ultraviolet
  • Impurità nell'acqua
    • Dissolved Gases
    • Inorganic Compounds
    • Microorganisms & Bacteria
    • Organic Compounds
    • Particulates
  • Conoscenza
    • BROSCHÜREN
    • Blog
    • Casi di studio
    • Acqua ultrapura
    • Guide e libri bianchi
  • Where to buy
  • Contattaci
  • A proposito di ELGA
    • A proposito di ELGA
    • Carriere
    • Eventi
  • Supporto
    • Laboratory Planning
  • Contatti
  • EN
  • DE
  • ES
  • FR
  • PT
  • EN-US
  • Normativa sulla privacy
  • Termini e condizioni
  • Dichiarazioni di conformità legale globale
  • Brevetti
  • Trademarks
  • Impressum
  • Challenges in the Purification of Drinking Water Part 1
Analytical Chemistry
Water Purity

Challenges in the Purification of Drinking Water Part 1

15 Feb 2021
- by Dr Paul Whitehead

Drinking Water

Transformation Products

One key role in making potable water “fit to drink” is to ensure that potentially toxic organic compounds are reduced to safe levels. This already challenging task is made even more challenging by the presence of additional compounds – so-called “transformation products” (TPs). These can take at least two forms:  new compounds formed when organics in water react in the environment and new compounds produced during the water purification processes themselves. The complexity of the chemistries involved is well illustrated by some recent work by Kiefer et al. on chlorothalonil TPs.1

Chlorothalonil, a fungicide used for decades worldwide, has recently been banned in the European Union (EU)2 and Switzerland due to its carcinogenicity and the presence of potentially toxic TPs in groundwater. However, its prolonged and extensive use has led to a build-up in water sources. Kiefer et al.1 have investigated the concentrations of a number of TPs of chlorothalonil  in 77 lakes, rivers and ground-waters and their removal during conventional water treatment and using other purification techniques. 

Environmental samples were enriched by vacuum-assisted evaporative concentration and separated by HPLC on a C18 column. Laboratory and field blanks, standards and spiked samples were treated in the same way. The injected volume was 150 μL corresponding to 15 mL of the original water sample. Samples were analysed in sequence, first in negative, then in positive electrospray ionization mode on an Orbitrap high-resolution mass spectrometer. Ultrapure water from an ELGA PURELAB Chorus I was used for the blanks and standards and for the preparation of the eluents. None of the analytes were found in the blanks.

Drinking Water Process

 

The chlorothalonil sulfonic acid TPs were found to occur more frequently and at higher concentrations (up to 2200 ngL−1) than the phenolic TPs (up to 130 ngL−1). The sulfonic acid TP R471811 was found in over half the samples to be above 100 ngL−1, the drinking water standard in Switzerland and other European countries. The removal of chlorothalonil TPs was investigated in laboratory and pilot-scale experiments and along the treatment train of various water works, comprising aquifer recharge, UV disinfection, ozonation, advanced oxidation processes (AOPs), activated carbon treatment, and reverse osmosis. The phenolic TPs can be broken down during ozonation and by reaction with hydroxyl radicals (radical dotOH) in AOPs. In contrast, the sulfonic acid TPs react only very slowly with ozone and radical dotOH and therefore persist after ozonation and radical dotOH-based AOPs. Activated carbon retained the very polar TP R471811 only up to a specific throughput. Reverse osmosis proved capable of removing all chlorothalonil TPs by ≥98%.

The widespread prevalence of TPs and their resistance to standard methods of water treatment is well illustrated by the example of chlorothalonil. It also demonstrates the need for the rigorous assessment of full environmental impact of new agricultural and industrial chemicals and their potential TPs.

Reference:

  1. Chlorothalonil transformation products in drinking water resources: Widespread and challenging to abate. Karin Kiefer, Tobias Bader, Nora Minas, Elisabeth Salhi, Elisabeth M.-L.Janssen, Ursvon Gunten, Juliane Hollender  Water Research, Vol 183, 15 September 2020, 116066 
  2. Commission implementing regulation (EU) 2019/677 of 29 April 2019 concerning the non-renewal of the approval of the active substance chlorothalonil.  Accordance with Regulation (EC) No 1107/2009 of the European Parliament and of the Council Concerning the Placing of Plant Protection Products on the Market, and Amending Commission Implementing Regulation (EU) No 540/2011, Official Journal of the European Union (2019)

 

Dr Paul Whitehead 

After a BA in Chemistry at Oxford University, Paul focused his career on industrial applications of chemistry. He was awarded a PhD at Imperial College, London for developing a microwave-induced-plasma detector for gas chromatography. He spent the first half of his career managing the analytical support team at the Johnson Matthey Research/Technology Centre,specialising in the determination of precious metals and characterising applications such as car-exhaust catalysts and fuel cells. Subsequently, as Laboratory Manager in R&D for ELGA LabWater, he has been involved in introducing and developing the latest water purification technologies. He now acts as a consultant for ELGA.

  • Sales Enquiry
  • Richiedi un Preventivo
  • Technical Support
  • Trova un Partner Approvato

Sales Enquiry

At ELGA LabWater, we have exciting offers and news about our products and services that we hope you’d like to hear about. We will use your information to predict what you might be interested in. We will treat your data with respect and you can find the details in our Privacy Policy.

ELGA LabWater works with a network of Approved Partners. In order to answer your questions or enquiries, we may pass your contact details to an Approved Partner, who may contact you directly. 

I'd like to receive updates from ELGA LabWater & ELGA Approved Partners based on my details.

Richiedi un Preventivo

At ELGA LabWater, we have exciting offers and news about our products and services that we hope you’d like to hear about. We will use your information to predict what you might be interested in. We will treat your data with respect and you can find the details in our Privacy Policy.

ELGA LabWater works with a network of Approved Partners. In order to answer your questions or enquiries, we may pass your contact details to an Approved Partner, who may contact you directly. 

I'd like to receive updates from ELGA LabWater & ELGA Approved Partners based on my details.

Technical Support

At ELGA LabWater, we have exciting offers and news about our products and services that we hope you’d like to hear about. We will use your information to predict what you might be interested in. We will treat your data with respect and you can find the details in our Privacy Policy.

ELGA LabWater works with a network of Approved Partners. In order to answer your questions or enquiries, we may pass your contact details to an Approved Partner, who may contact you directly. 

Call us

Can't find what you are looking for?

Support Number
+44 (0)20 3567 7300
United Kingdom Sales
+44 (0)1628 879 704
United States of America Sales
+1 877-315-3542
France Sales
+33 1 40 83 65 00
China Sales
+86 400-616-8882

 

ELGA LabWater Sede Centrale

Lane End Business Park
Lane End, High Wycombe
HP14 3BY
United Kingdom
T: +44 (0) 203 567 7300
F: +44 (0) 203 567 7205

Casi di Studio

  • Abbott Diagnostics
  • DASA Diagnostica Medica
  • NeoDIN Istituto Medico
  • North Staffordshire NHS Trust
  • Scuola Professionale Olsberg

Risorse

  • Informazioni sull'acqua ultrapura
  • Guide e libri bianchi
  • Tecnologie per la purificazione dell'acqua
  • Applicazioni di laboratorio
  • Impurità nell'acqua
  • Latest Blog
  • Water Purity - Different Types of Pure Water
  • What is Clinical Laboratory Reagent Water (CLSI)?
  • What is Total Organic Carbon (TOC)?

© VWS (UK) Ltd. che opera come ELGA LabWater. 2025 - Tutti i diritti riservati.
ELGA è il marchio mondiale dell'acqua di laboratorio di Veolia.

  • Normativa sulla privacy
  • Termini e condizioni
  • Dichiarazioni di conformità legale globale
  • Brevetti
  • Trademarks
  • Impressum
  • Lingua
    • Deutsch
    • English
    • Español
    • Français
    • Italiano
    • Português
    • 日本語
    • 中文
  • Altri Siti Veolia
    • Veolia
    • Veolia Foundation
    • Veolia Water Technologies
Elga Veolia
TOP

© 2017 ELGA Veolia